Murphy Lab - Synthesis

[1] Possible Synthetic Approaches for Heterobimetallic Complexes by Using NHC/NHC Heteroditopic Carbene Ligands.

[2] Erratum: Percent buried volume for phosphine and N-heterocyclic carbene ligands: Steric properties in organometallic chemistry (Chemical Communications (2010) 46 (841-861) DOI: 10.1039/b922984a)

[3] N-Heterocyclic carbene–copper complex supported on ionic liquid-modified graphene oxide: versatile catalyst for synthesis of (i) 1,2,3-triazole and (ii) propargylamine derivatives

[4] DFT based engineering of N-heterocyclic carbenes to exacerbate its activity for SO fixation and storage.

[5] Predictive Model for the [Rh<inf>2</inf>(esp)<inf>2</inf>]-Catalyzed Intermolecular C(sp³)-H Bond Insertion of β-Carbonyl Ester Carbenes: Interplay between Theory and Experiment

[6] Synthesis and structural characterization of benzyl-functionalized N-heterocyclic carbene platinum complexes: Dramatic substituent effect on anti-cancer activity

[7] Blue Phosphorescent trans-N-Heterocyclic Carbene Platinum Acetylides. Dependence on Energy Gap and Conformation.

[8] B-B Cleavage and Ring-Expansion of a 1,4,2,3-Diazadiborinine with N-Heterocyclic Carbenes.

[9] Synthesis and structural characterization of 20-membered macrocyclic rings bearing trans-chelating bis(N-heterocyclic carbene) ligands and the catalytic activity of their palladium(ii) complexes.

[10] Synthesis of trans-Isotactic Poly(norbornene)s through Living Ring-Opening Metathesis Polymerization Initiated by Group VI Imido Alkylidene N-Heterocyclic Carbene Complexes

[11] Stereoelectronic Profiling of Expanded-Ring N-Heterocyclic Carbenes

[12] Heterogeneous catalysts based on built-in N-heterocyclic carbenes with high removability, recoverability and reusability for ring-opening polymerization of cyclic esters

[13] Mesoionic 1,2,3-Triazoles and 1,2,3-Triazole Carbenes

[14] Synthesis of podophyllotoxin-glycosyl triazoles click protocol mediated by silver (I)--heterocyclic carbenes and their anticancer evaluation as topoisomerase-II inhibitors.

[15] Dihydrogen activation by intermolecular rare-earth aryloxide/N-heterocyclic carbene Lewis pairs.

[16] Electrolyte tuning in dye-sensitized solar cells with N-heterocyclic carbene (NHC) iron(II) sensitizers

[17] Synthesis and characterisation of Pd(ii) and Au(i) complexes with mesoionic carbene ligands bearing phosphinoferrocene substituents and isomeric carbene moieites.

[18] -Heterocyclic Carbene-Platinum Complexes Featuring an Anthracenyl Moiety: Anti-Cancer Activity and DNA Interaction.

[19] Green synthesis of selenium-N-heterocyclic carbene compounds: Evaluation of antimicrobial and anticancer potential.

[20] Chemistry of polynuclear metal complexes with bridging carbene or carbyne ligands. Part 96. Reactions with phospha-alkynes; crystal structures of [WFe{μ-C(C<inf>6</inf>H<inf>4</inf>Me-4)PC(Bu^t)(CO) <inf>5</inf>}(η-C<inf>5</inf>Me<inf>5</inf>)] and [MoFe{μ-C(C <inf>6</inf>H<inf>4</inf>Me-4)C(Bu^t)P}(μ-CO)(CO) <inf>3</inf>(PMe<inf>3</inf>)...

[21] Synthesis of 1,3-oxaphospholes via chromium mediated cyclization of carbenes, carbon monoxide, and phospha-alkynes

[22] Synthesis of 1,3-oxaphospholes via chromium mediated cyclization of carbenes, carbon monoxide, and phospha-alkynes

[23] Ultrasound assisted dispersive solid phase extraction of triazole fungicides by using an N-heterocyclic carbene copper complex supported on ionic liquid-modified graphene oxide as a sorbent

[24] N-Heterocyclic carbene–rhodium complexes as catalysts for hydroformylation and related reactions

[25] organic-inorganic hybrid silica material derived from a monosilylated grubbs-hoveyda ruthenium carbene as a recyclable metathesis catalyst

[26] suzuki-miyaura reactions catalyzed by c2-symmetric pd-multi-dentate n-heterocyclic carbene complexes

[27] n-heterocyclic carbene catalyzed synthesis of dimethyl carbonate via transesterification of ethylene carbonate with methanol

[28] A de novo peroxidase is also a promiscuous yet stereoselective carbene transferase

[29] Catalytic and Biocatalytic Iron Porphyrin Carbene Formation: Effects of Binding Mode, Carbene Substituent, Porphyrin Substituent, and Protein Axial Ligand

[30] Catalytic Cyclopropanation by Myoglobin Reconstituted with Iron Porphycene: Acceleration of Catalysis due to Rapid Formation of the Carbene Species

[31] Catalytic and Biocatalytic Iron Porphyrin Carbene Formation: Effects of Binding Mode, Carbene Substituent, Porphyrin Substituent, and Protein Axial Ligand

[32] Remarkably stable iron porphyrins bearing nonheteroatom-stabilized carbene or (alkoxycarbonyl)carbenes: isolation, X-ray crystal structures, and carbon atom transfer reactions with hydrocarbons

[33] Intermolecular carbene S–H insertion catalysed by engineered myoglobin-based catalysts

[34] Olefin cyclopropanation via carbene transfer catalyzed by engineered cytochrome P450 enzymes

[35] A Serine-Substituted P450 Catalyzes Highly Efficient Carbene Transfer to Olefins In Vivo

[36] Novel 3,4-dihydro-1,4-oxazine (dehydromorpholine) sulfonamides and sulfones conveniently accessed from suitable a-diazoketones via O[sbnd]H carbene insertion – Cyclization sequence