Catalytic and Biocatalytic Iron Porphyrin Carbene Formation: Effects of Binding Mode, Carbene Substituent, Porphyrin Substituent, and Protein Axial Ligand
Abstract
Iron porphyrin carbenes (IPCs) are important intermediates in various chemical reactions catalyzed by iron porphyrins and engineered heme proteins, as well as in the metabolism of various xenobiotics by cytochrome P450. However, there are no prior theoretical reports to help understand their formati …
Keywords
catalysis
National Center for Biotechnology Information
NCBI
NLM
MEDLINE
Molecular
pubmed abstract
nih
national institutes of health
national library of medicine
Thermodynamics
models
research support
u.s. gov't
non-p.h.s.
N.I.H.
Extramural
ligands
yong zhang
methane / metabolism
hemeproteins / metabolism
pmid:26067900
pmc4482416
doi:10.1021/jacs.5b03437
rahul l khade
biocatalysis
cytochrome p-450 enzyme system / metabolism
iron compounds / chemistry*
iron compounds / metabolism
metalloporphyrins / chemistry*
metalloporphyrins / metabolism
methane / analogs & derivatives*
methane / chemistry
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268263
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