suzuki-miyaura reactions catalyzed by c2-symmetric pd-multi-dentate n-heterocyclic carbene complexes
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suzuki-miyaura reactions catalyzed by c2-symmetric pd-multi-dentate n-heterocyclic carbene complexes

;Zhengning Li;Defeng Zhao;Fengjun Shan;Lan Jiang
Journal of ethnopharmacology 2012 Vol. 17 pp. 12121-12139
255
li2012moleculessuzuki-miyaura

Abstract

Suzuki-Miyaura coupling reactions are promoted by Pd complexes ligated with C2-symmetric multi-dentate N-heterocyclic carbenes derived in situ from Pd(OAc)2 and imidazolium salts. Good to excellent yields were obtained for aryl bromides as substrates. Turnover numbers of up to 105 could be achieved with 5 × 10−4 mol% of Pd(OAc)2/1 × 10−3 mol% NHC precatalyst in 24 h.

Keywords

n-heterocyclic carbene imidazolium salt palladium catalysisorganic chemistry suzuki-miyaura coupling

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DOI:
10.3390/molecules171012121
URL:
http://www.mdpi.com/1420-3049/17/10/12121

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ID: 232572
Ref Key: li2012moleculessuzuki-miyaura
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