organic-inorganic hybrid silica material derived from a monosilylated grubbs-hoveyda ruthenium carbene as a recyclable metathesis catalyst
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organic-inorganic hybrid silica material derived from a monosilylated grubbs-hoveyda ruthenium carbene as a recyclable metathesis catalyst

;Michel Wong Chi Man;Ramón Alibés;Xavier Cattoën;Guadalupe Borja;Roser Pleixats
Journal of ethnopharmacology 2010 Vol. 15 pp. 5756-5767
210
man2010moleculesorganic-inorganic

Abstract

The synthesis of a monosilylated Grubbs-Hoveyda ruthenium alkylidene complex is described, as well as the preparation and characterization of the corresponding material by sol-gel cogelification with tetraethoxysilane (TEOS) and the assay of this recyclable supported catalyst in ring-closing diene and enyne metathesis reactions under thermal and microwave conditions.

Keywords

ring-closing metathesis

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DOI:
10.3390/molecules15085756
URL:
http://www.mdpi.com/1420-3049/15/8/5756/

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ID: 213548
Ref Key: man2010moleculesorganic-inorganic
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