Remarkably stable iron porphyrins bearing nonheteroatom-stabilized carbene or (alkoxycarbonyl)carbenes: isolation, X-ray crystal structures, and carbon atom transfer reactions with hydrocarbons
Abstract
Reactions of [Fe(TPFPP)] (TPFPP = meso-tetrakis(pentafluorophenyl)porphyrinato dianion) with diazo compounds N(2)C(Ph)R (R = Ph, CO(2)Et, CO(2)CH(2)CH=CH(2)) afforded [Fe(TPFPP)(C(Ph)R)] (R = Ph (1), CO(2)Et (2), CO(2)CH(2)CH=CH(2) (3)) in 65-70% yields. Treatment of 1 with N-methylimidazole (MeIm) …
Keywords
National Center for Biotechnology Information
NCBI
NLM
MEDLINE
Molecular
pubmed abstract
nih
national institutes of health
national library of medicine
models
research support
non-u.s. gov't
Methane / chemistry*
molecular structure
yan li
x-ray
iron / chemistry*
porphyrins / chemistry*
methane / analogs & derivatives*
crystallography
pmid:12405847
doi:10.1021/ja020391c
jie-sheng huang
xiao-zeng you
carbon / chemistry
ferric compounds / chemistry
hydrocarbons / chemistry*
metalloporphyrins / chemistry
methane / isolation & purification
porphyrins / isolation & purification
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270320
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