Catalytic Cyclopropanation by Myoglobin Reconstituted with Iron Porphycene: Acceleration of Catalysis due to Rapid Formation of the Carbene Species
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Catalytic Cyclopropanation by Myoglobin Reconstituted with Iron Porphycene: Acceleration of Catalysis due to Rapid Formation of the Carbene Species

Oohora K;Meichin H;Zhao L;Wolf MW;Nakayama A;Hasegawa JY;Lehnert N;Hayashi T;;
Journal of the American Chemical Society 2017 Vol. 139 pp. -
193
k2017journalcatalytic

Abstract

Myoglobin reconstituted with iron porphycene catalyzes the cyclopropanation of styrene with ethyl diazoacetate. Compared to native myoglobin, the reconstituted protein significantly accelerates the catalytic reaction and the kcat/Km value is 26-fold enhanced. Mechanistic studie …

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National Center for Biotechnology Information NCBI NLM MEDLINE pubmed abstract nih national institutes of health national library of medicine research support non-u.s. gov't pmid:29148750 doi:10.1021/jacs.7b10154 koji oohora hiroyuki meichin takashi hayashi

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