SNYTHESIS AND CHARACTERIZATION OF HYDRATED TRIS (2, 2'- BIPYRIDINE) DICHLORIDE RUTHENIUM (II) COMPLEX AND ITS ELECTROCATALYTIC ACTIVITY TOWARDS CARBON DI OXIDE REDUCTION
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Asghar Khan,
Ho Shik Won,
J Ong Chem Res, 2014, 1 (3), 83-97, doi: , ISSN 2651-4338
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Abstract:
A new convenient method for the synthesis of hydrated tris (2, 2'-bipyridine) dichloride ruthenium (II) complex has been developed. We introduced the chlorosulfonic acid as a chlorinating reagent during our synthetic process which replace the hexafluorophosphate radical of the [Ru (bpy) 3] (PF6)2 complex with chloride, form hydrated Tris [Ru (bpy) 3] (Cl)2 complex. The corresponding complex is characterized with UV-Visible, IR, CV, 1 H and C 13 NMR spectroscopic technique. The synthesized hydrated ruthenium complex was then checked as an electrocatalyst for the reduction of carbon dioxide in a designed electrolytic cell. The carbon dioxide gas in the aqueous solution of Tris (2, 2'-bipyridine) ruthenium (II) dichloride catalyst, at the potential of 1.5 V reduced to methane gas, examined with FTIR spectrometer.
Keywords:
Chlorosulfonic acid,
2,2'-bipyridine,
Spectroscopic study,
Cyclic voltammetry,
Electrocatalytic reduction,
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Asghar Khan, Ho Shik Won, (2014). SNYTHESIS AND CHARACTERIZATION OF HYDRATED TRIS (2, 2'- BIPYRIDINE) DICHLORIDE RUTHENIUM (II) COMPLEX AND ITS ELECTROCATALYTIC ACTIVITY TOWARDS CARBON DI OXIDE REDUCTION, Journal of Ongoing Chemical Research, 1(3): 83-97
@article{asghar_khan2014jocr,
author = {Asghar Khan and Ho Shik Won},
title = {SNYTHESIS AND CHARACTERIZATION OF HYDRATED TRIS (2, 2'- BIPYRIDINE) DICHLORIDE RUTHENIUM (II) COMPLEX AND ITS ELECTROCATALYTIC ACTIVITY TOWARDS CARBON DI OXIDE REDUCTION},
journal = {Journal of Ongoing Chemical Research},
year = {2014},
volume = {1},
number = {3},
pages = {83-97},
doi = {},
url = {https://scimatic.org/show_manuscript/111}
}
