ON THE PECULIARITIES OF THE RING CONTRACTION REACTIONS OF HOMODRIMANES VIA ACID MEDIATED EPOXIDE REARRANGEMENT
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ON THE PECULIARITIES OF THE RING CONTRACTION REACTIONS OF HOMODRIMANES VIA ACID MEDIATED EPOXIDE REARRANGEMENT

Kulciţki, Veaceslav;Sîrbu, Tatiana;Ungur, Nicon;
chemistry journal of moldova: general, industrial and ecological chemistry 2011 Vol. 6 pp. 110-112
61
kulciki2011onchemistry

Abstract

A selective rearrangement of a epoxy-homodrimanic substrate is described. Using fluorosulfonic acid at low temperature leads by ring contraction to a perhydrindanic structure. On the contrary, using boron trifluoride-diethyl ether at r.t. selectively brings about angular methyl migration.

Keywords

chemistry Biotechnology Pediatrics physics geography (general) neurosciences. biological psychiatry. neuropsychiatry mathematics crystallography international relations auxiliary sciences of history history of civilization general. including alchemy

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