the electron donating properties of nitrogen-containing organic bases in mixed media
;A. N. Chebotaryov;D. V. Snigur;K. V. Bevziuk;S. V. Kachan;O. S. Chernyi
Nature communications2014Vol. 17pp. 29-36
45
chebotaryov2014vsnikthe
Abstract
The thermodynamic ionization constants of aniline, pyridine and octylamine in waterdimethylformamide and water-dioxane media were determined by potentiometric titration method. Mathematical models that adequately describe the change of the nitrogencontaining organic bases рК were constructed by varying characteristics of chemical systems.