Structural relationship between a host included chain of spirocyclic water hexamers and bulk water--the role of water clusters in self assembly and crystallization processes.
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Structural relationship between a host included chain of spirocyclic water hexamers and bulk water--the role of water clusters in self assembly and crystallization processes.

Luna-García, Rolando;Damián-Murillo, Berenice M;Barba, Victor;Höpfl, Herbert;Beltrán, Hiram I;Zamudio-Rivera, Luis S;
Chemical communications (Cambridge, England) 2005 pp. 5527-9
218
lunagarca2005structuralchemical

Abstract

Infinite chains of spirocyclic water hexamers are included in the crystal lattice of a tin complex with a curved, hydrophobic surface and only weak intermolecular bonding interactions between the host molecules, so that the enclosed water clusters might be reminiscent of the solvation sphere in solution.

Keywords

crystal structure hydrogen bonds n,n′-di­cyclo­hexyl­carbodimide n,n′-di­cyclo­hexyl­urea

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