Ag(μ-S)(p-TBBT)(PPh): symmetry breaking induced by the core to generate chirality.
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Ag(μ-S)(p-TBBT)(PPh): symmetry breaking induced by the core to generate chirality.

Tian, Fan;Chen, Rong;
Chemical communications (Cambridge, England) 2020
231
tian2020agsptbbtpphchemical

Abstract

A chiral silver-sulfur nanocluster with a μ8-S inside, Ag18(μ8-S)(p-TBBT)16(PPh3)8, was successfully synthesized and characterized. This nanocluster is composed of a crown-like Ag8S core and an Ag10S16P8 meso-shell. The presence of the core induces symmetry breaking of the nanocluster from S8 to C4, and therefore endows the cluster with chirality.

Keywords

amine-imine-exchange strategy morphological transformation orthogonal dynamic covalent self-assembly polymer nanocapsules and thin films

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DOI:
10.1039/c9cc10045h

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ID: 92624
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