Multi-port measurements are a big challenge in circuits' verification, especially when the frequency increases. This study presents a new technique for measuring S-parameters of multi-port ultra-wideband (UWB) microwave and mm-wave circuits. The concepts are based on direct or indirect applying modulated UWB impulse radio in desired bandwidth to the one port of the modified multi-port circuit and gathering the reflected signal in the same port and the output signal in the second port in time domain, and the other ports are left opened with a special designed added electrical length. Then by applying intelligent windowing in time domain to the gathering data, and using fast Fourier transform, the desired S-parameters are extracted. Validation of this technique is verified by design and fabrication of a three-port UWB Wilkinson power divider in 22–30 GHz. The simulation and measurement results of the reflection and transmission S-parameters by using this new technique are very close to those are extracted with the conventional vector network analysers S-parameters measurements and show the ability and the accuracy of this technique.