Fast traveling waves in the phase-field theory: effective mobility approach versus kinetic energy approach.

Fast traveling waves in the phase-field theory: effective mobility approach versus kinetic energy approach.

Galenko, Peter;Salhoumi, Ahmed;
journal of physics condensed matter : an institute of physics journal 2020
208
galenko2020fastjournal

Abstract

A phase-field model for small and large driving forces on solidification and melting of a pure substance or alloys is formulated. Derivations of the phase-field model are based on the effective mobility approach and on the kinetic energy approach to analyze fast phase transformation from metastable liquid to solid phase. A hodograph equation (an acceleration-velocity dependent equation of the Gibbs-Thomson type) which predicts the non-linear behavior in the velocity of the crystal-liquid interface is found at the large driving force on transformation and analyzed for different thermodynamic potentials. Traveling wave solutions of this equation are found for double-well and double-obstacle potentials. The velocity-dependent traveling waves as a function of driving force on transformation exhibits non-linearity of the solutions. Namely, in the relationship "velocity - driving force'' exists a maximum at a fixed undercooling which is very well known in the solidification of glass-forming metals and alloys. The predicted solidification velocity is quantitatively compared with the molecular dynamics simulation data obtained by Tang and Harrowell [Nature Materials {\bf 12} (2013) 507] for the solidification of congruently melting Cu-Zr binary alloy. The comparison confirms a crucial role of local non-equilibrium such as relaxation of gradient flow in the quantitative description of fast phase transformations.

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0x95644003c57E6F55A65596E3D9Eac6813e3566dA
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84339
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10.1088/1361-648X/ab6ae9
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Scimatic Chain (ID: 481)
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