Ethyl (1R,4S,5R,9S,10R,13S)-5,9,13-trimethyl-14-methylene-14-oxotetracyclo[11.2.1.01,10.04,9]hexadecane-5-carboxylate

Ethyl (1R,4S,5R,9S,10R,13S)-5,9,13-trimethyl-14-methylene-14-oxotetracyclo[11.2.1.01,10.04,9]hexadecane-5-carboxylate

Shi, Hao;
acta crystallographica section e 2010 Vol. 66 pp. o154-o154
171
shi2010ethylacta

Abstract

The title compound, C22H34O3, was synthesized from isosteviol. The asymmetric unit contains of two independent molecules with the same absolute configurations. In both the molecules, the three six-membered rings adopt chair conformations, the stereochemistry of the A/B and B/C ring junctions are trans, and the five-membered ring D adopts an envelope conformation.

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