Structurally Isomerized Bis-Biphenyl Moieties Embedded in Hexaphyrin(3.1.1.3.1.1) and Octaphyrin(1.1.1.0.1.1.1.0).
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Structurally Isomerized Bis-Biphenyl Moieties Embedded in Hexaphyrin(3.1.1.3.1.1) and Octaphyrin(1.1.1.0.1.1.1.0).

Chitranshi, Sangya;Das, Mainak;Adinarayana, B;Cha, Won-Young;Kim, Dongho;Srinivasan, A;
Organic letters 2020
188
chitranshi2020structurallyorganic

Abstract

An --biphenyl moiety-incorporated 32π hexaphyrin(3.1.1.3.1.1) is successfully achieved. Replacing with connectivity in the biphenyl unit of hexaphyrin leads to the formation of its structural isomer, octaphyrin(1.1.1.0.1.1.1.0). Spectral and structural analyses reveal the lack of planarity in hexaphyrin and the presence of an -arene unit in octaphyrin, thus affording nonaromatic characteristics.

Keywords

melanoma metastasis gpx4 prc2 cdr1as ezh2 igf2bp linc00632 circrna mir-7

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DOI:
10.1021/acs.orglett.9b04614

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ID: 80650
Ref Key: chitranshi2020structurallyorganic
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