Diarylbiindolinones as Substituent-Tunable Mechanochromophores and Their Application in Mechanochromic Polymers.

Diarylbiindolinones as Substituent-Tunable Mechanochromophores and Their Application in Mechanochromic Polymers.

Kawasaki, Kazuma;Aoki, Daisuke;Otsuka, Hideyuki;
Macromolecular rapid communications 2019 pp. e1900460
171
kawasaki2019diarylbiindolinonesmacromolecular

Abstract

The synthesis and characterization of a series of diarylbiindolinone derivatives as substituent-tunable mechanochromophores that generate pink carbon-centered radicals in response to mechanical stimuli are reported. The changes in mechano-responsiveness, which result from the introduction of various substituents on the diarylbiindolinone skeleton, are systematically studied and mechanochromic polymers that contain such diarylbiindolinone units are developed.

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ID: 71668
Ref Key: kawasaki2019diarylbiindolinonesmacromolecular
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71668
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