Copper-Catalyzed Three-Component Reaction of Alkynes, TMSN, and Ethers: Regiocontrollable Synthesis of N- and N-Oxyalkylated 1,2,3-Triazoles.
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Copper-Catalyzed Three-Component Reaction of Alkynes, TMSN, and Ethers: Regiocontrollable Synthesis of N- and N-Oxyalkylated 1,2,3-Triazoles.

Bao, Pengli;Yue, Huilan;Meng, Na;Zhao, Xiaohui;Li, Jiangsheng;Wei, Wei;
Organic letters 2019 Vol. 21 pp. 7218-7222
294
bao2019coppercatalyzedorganic

Abstract

A new copper-catalyzed selective synthesis of N- and N-oxyalkylated 1,2,3-triazoles has been developed through a three-component reaction of alkynes, TMSN, and ethers. Through this methodology, a series of N- and N-oxyalkylated 1,2,3-triazoles could be efficiently and regioselectively obtained from simple and readily available starting materials with favorable functional group tolerance.

Keywords

2 1 Docking Triazole DFT qsar 3]triazolo[4 5-d]pyrimidine analogues pyrimidine

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DOI:
10.1021/acs.orglett.9b02295

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ID: 50531
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