(E)-1-[1-(3-Phenylcyclopenta-2,4-dien-1-ylidene)ethyl]pyrrolidine

(E)-1-[1-(3-Phenylcyclopenta-2,4-dien-1-ylidene)ethyl]pyrrolidine

Peloquin, Andrew J.;Smith, Madelyn B.;Balaich, Gary J.;Iacono, Scott T.;
iucrdata 2018 Vol. 3 pp. x180764-
369
peloquin2018e113phenylcyclopenta24dien1ylideneethylpyrrolidineiucrdata

Abstract

The title compound, C17H19N, is a disubstituted pentafulvene obtained from the hydroamination of 1-phenyl-3-trimethylsilylethynylcyclopentadiene and has monoclinic P21/n symmetry at 100 K. C—H...π ring interactions between neighboring molecules consolidate the packing. To the authors' knowledge, this reaction is the first reported example of a non-transition metal catalyzed hydroamination with concomitant desilylation.

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