Recent Advances in Acyl Suzuki Cross-Coupling

Recent Advances in Acyl Suzuki Cross-Coupling

Buchspies, Jonathan;Szostak, Michal;
catalysts 2019 Vol. 9 pp. 53-
195
buchspies2019recentcatalysts

Abstract

Acyl Suzuki cross-coupling involves the coupling of an organoboron reagent with an acyl electrophile (acyl halide, anhydride, ester, amide). This review provides a timely overview of the very important advances that have recently taken place in the acylative Suzuki cross-coupling. Particular emphasis is directed toward the type of acyl electrophiles, catalyst systems and new cross-coupling partners. This review will be of value to synthetic chemists involved in this rapidly developing field of Suzuki cross-coupling as well as those interested in using acylative Suzuki cross-coupling for the synthesis of ketones as a catalytic alternative to stoichiometric nucleophilic additions or Friedel-Crafts reactions.

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