Cooperative adsorption of carbon disulfide in diamine-appended metal–organic frameworks
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Cooperative adsorption of carbon disulfide in diamine-appended metal–organic frameworks

McGuirk, C. Michael;Siegelman, Rebecca L.;Drisdell, Walter S.;Runčevski, Tomče;Milner, Phillip J.;Oktawiec, Julia;Wan, Liwen F.;Su, Gregory M.;Jiang, Henry Z. H.;Reed, Douglas A.;Gonzalez, Miguel I.;Prendergast, David;Long, Jeffrey R.;
Nature communications 2018 Vol. 9 pp. 1-10
156
mcguirk2018cooperativenature

Abstract

The large-scale production of CS2 presents both environmental and biological hazards, yet adsorbents capable of CS2 capture remain scarcely explored. Here, Long and colleagues demonstrate that CS2 is adsorbed in diamine-appended metal–organic frameworks through a cooperative and chemically specific insertion process.

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