Screen-Printed Soft-Nitrided Carbon Electrodes for Detection of Hydrogen Peroxide.

Screen-Printed Soft-Nitrided Carbon Electrodes for Detection of Hydrogen Peroxide.

Ogbu, Chidiebere I;Feng, Xu;Dada, Samson N;Bishop, Gregory W;
Sensors (Basel, Switzerland) 2019 Vol. 19
237
ogbu2019screenprintedsensors

Abstract

Nitrogen-doped carbon materials have garnered much interest due to their electrocatalytic activity towards important reactions such as the reduction of hydrogen peroxide. N-doped carbon materials are typically prepared and deposited on solid conductive supports, which can sometimes involve time-consuming, complex, and/or costly procedures. Here, nitrogen-doped screen-printed carbon electrodes (N-SPCEs) were fabricated directly from a lab-formulated ink composed of graphite that was modified with surface nitrogen groups by a simple soft nitriding technique. N-SPCEs prepared from inexpensive starting materials (graphite powder and urea) demonstrated good electrocatalytic activity towards hydrogen peroxide reduction. Amperometric detection of HO using N-SPCEs with an applied potential of -0.4 V (vs. Ag/AgCl) exhibited good reproducibility and stability as well as a reasonable limit of detection (2.5 µM) and wide linear range (0.020 to 5.3 mM).

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