We demonstrate a mode-locked erbium-doped fiber laser (EDFL) utilizing copper phthalocyanines (CuPc) as a saturable absorber (SA) for the first time, to the best of our knowledge. The investigated SA was prepared using a simple, low-cost and straightforward technique, whereby the CuPc powder was embedded into polyvinyl alcohol (PVA) to form a thin film. The thin film acted as a mode-locker when it was incorporated into the EDFL cavity to produce output pulses at a repetition rate of 1.8 MHz with a pulse duration of 1.98 ps. The frequency spectrum showed a signal-to-noise ratio as high as 55 dB, which indicates the stability of the mode-locking operation. To the best of our knowledge, this is the first work to report using CuPc as a mode-locker.