4-Meth-oxy-2-[(E)-(phenyl-imino)meth-yl]phenol.

4-Meth-oxy-2-[(E)-(phenyl-imino)meth-yl]phenol.

Uçan, Selma;Oztürk, Aslı;Sarıkavaklı, Nursabah;Hökelek, Tuncer;
Acta crystallographica. Section E, Structure reports online 2008 Vol. 64 pp. o1818-9
44
ucan20084methoxy2ephenyliminomethylphenolacta

Abstract

In the mol-ecule of the title compound, C(14)H(13)NO(2), the two aromatic rings are oriented at a dihedral angle of 0.78 (20)°; with the exception of two methyl H atoms the mol-ecule is essentially planar. The intra-molecular O-H⋯N hydrogen bond results in the formation of a non-planar, six-membered ring, which adopts a flattened-boat conformation. In the crystal structure, inter-molecular C-H⋯O hydrogen bonds link the mol-ecules to form parallel networks. There is a C-H⋯π contact between the methyl group and the benzene ring. A π-π contact between the benzene and phenyl rings [centroid-centroid distance = 4.681 (5) Å] is also observed.

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ID: 276949
Ref Key: ucan20084methoxy2ephenyliminomethylphenolacta
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