Volumetric behaviour of binary liquid systems composed of toluene, isooctane, and methyl tert-butyl ether at temperatures from (298.15 to 328.15)K

Volumetric behaviour of binary liquid systems composed of toluene, isooctane, and methyl tert-butyl ether at temperatures from (298.15 to 328.15)K

L. Morávková,Z. Wagner,J. Linek;L. Morávková;Z. Wagner;J. Linek;
The Journal of Chemical Thermodynamics 2009 Vol. 41 pp. 591-597
189
linek2009thevolumetric

Abstract

The densities and speeds of sound of (toluene + isooctane), (MTBE + toluene), and (MTBE + isooctane) were measured at four temperatures from (298.15 to 328.15) K, and the respective values of excess volumes VmE and adiabatic compressibility κ S were calculated. The VmE and κ S values were fitted to the fourth-order Redlich–Kister equation. The VmE values for (MTBE + toluene) are negative and decreasing with increasing temperature. The other systems show positive VmE with comparatively small temperature dependence.

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ID: 271568
Ref Key: linek2009thevolumetric
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271568
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10.1016/j.jct.2009.01.008
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