Recent Advances in Electrochemiluminescence and Chemiluminescence of Metal Nanoclusters

Recent Advances in Electrochemiluminescence and Chemiluminescence of Metal Nanoclusters

Shuang Han;Yuhui Zhao;Zhichao Zhang;Guobao Xu;Han, Shuang;Zhao, Yuhui;Zhang, Zhichao;Xu, Guobao;
molecules 2020 Vol. 25 pp. 5208-
229
han2020moleculesrecent

Abstract

Metal nanoclusters (NCs), including Au, Ag, Cu, Pt, Ni and alloy NCs, have become more and more popular sensor probes with good solubility, biocompatibility, size-dependent luminescence and catalysis. The development of electrochemiluminescent (ECL) and chemiluminescent (CL) analytical methods based on various metal NCs have become research hotspots. To improve ECL and CL performances, many strategies are proposed, from metal core to ligand, from intermolecular electron transfer to intramolecular electron transfer. Combined with a variety of amplification technology, i.e., nanostructure-based enhancement and biological signal amplification, highly sensitive ECL and CL analytical methods are developed. We have summarized the research progresses since 2016. Also, we discuss the current challenges and perspectives on the development of this area.

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