Capture and characterization of a reactive haem–carbenoid complex in an artificial metalloenzyme - Nature Catalysis
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Capture and characterization of a reactive haem–carbenoid complex in an artificial metalloenzyme - Nature Catalysis

Hayashi, Takahiro;Tinzl, Matthias;Mori, Takahiro;Krengel, Ute;Proppe, Jonny;Soetbeer, Janne;Klose, Daniel;Jeschke, Gunnar;Reiher, Markus;Hilvert, Donald;Hayashi, Takahiro;Tinzl, Matthias;Mori, Takahiro;Krengel, Ute;Proppe, Jonny;Soetbeer, Janne;Klose, Daniel;Jeschke, Gunnar;Reiher, Markus;Hilvert, Donald;
nature catalysis 2018 Vol. 1 pp. 578-584
232
takahiro2018naturecapture

Abstract

A haem–carbenoid has been proposed to be involved in abiological enzymatic reactions. Now, Hilvert and co-workers provide crystallographic evidence for a haem–carbenoid intermediate as the reactive species in an olefin cyclopropanation reaction catalysed by an artificial metalloenzyme.

Keywords

Biocatalysis X-ray crystallography enzymes iron enzyme mechanisms

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DOI:
doi:10.1038/s41929-018-0105-6
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https://dx.doi.org/10.1038/s41929-018-0105-6##auth...

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