Nonstoichiometric copper chalcogenides for photo-activated alkyne/azide cycloaddition
Hong Yan Zou;Hong Yan Zou;Ming Xuan Gao;Ming Xuan Gao;Tong Yang;Tong Yang;Qiao Ling Zeng;Qiao Ling Zeng;Xiao Xi Yang;Xiao Xi Yang;Feng Liu;Feng Liu;Mark T. Swihart;Mark T. Swihart;Na Li;Na Li;Cheng Zhi Huang;Cheng Zhi Huang;
physical chemistry chemical physics2017Vol. 19pp. 6964-6968
116
zou2017physicalnonstoichiometric
Abstract
Nonstoichiometric copper chalcogenides with heavy copper vacancies can be used as an effective photo-activated catalyst for the Huisgen [3+2] cycloaddition reaction as Cu(i) can be released corresponding to holes (Cu-defects) under light irradiation. These strategies expand new possibilities for carrying out