Capture and characterization of a reactive haem–carbenoid complex in an artificial metalloenzyme - Nature Catalysis
Current Language EN
English English Türkçe Türkçe Español Español Português Português Pусский Pусский Filipino Filipino Tiếng Việt Tiếng Việt हिन्दी हिन्दी العربية العربية বাংলা বাংলা Deutsch Deutsch 中文 中文

Capture and characterization of a reactive haem–carbenoid complex in an artificial metalloenzyme - Nature Catalysis

Takahiro Hayashi;Matthias Tinzl;Takahiro Mori;Ute Krengel;Jonny Proppe;Janne Soetbeer;Daniel Klose;Gunnar Jeschke;Markus Reiher;Donald Hilvert;Takahiro Hayashi;Matthias Tinzl;Takahiro Mori;Ute Krengel;Jonny Proppe;Janne Soetbeer;Daniel Klose;Gunnar Jeschke;Markus Reiher;Donald Hilvert;
nature catalysis 2018 Vol. 1 pp. 578-584
264
hayashi2018naturecapture1

Abstract

A haem–carbenoid has been proposed to be involved in abiological enzymatic reactions. Now, Hilvert and co-workers provide crystallographic evidence for a haem–carbenoid intermediate as the reactive species in an olefin cyclopropanation reaction catalysed by an artificial metalloenzyme.

Keywords

Biocatalysis X-ray crystallography enzymes iron enzyme mechanisms

Access

DOI:
doi:10.1038/s41929-018-0105-6
URL:
https://dx.doi.org/10.1038/s41929-018-0105-6##auth...

Citation

ID: 267715
Ref Key: hayashi2018naturecapture1
Use this key to autocite in SciMatic or Thesis Manager

References

References

No Bibliography

Blockchain Verification

Account:
NFT Contract Address:
0x95644003c57E6F55A65596E3D9Eac6813e3566dA
Article ID:
267715
Unique Identifier:
doi:10.1038/s41929-018-0105-6
Network:
Scimatic Chain (ID: 481)
Blockchain Readiness Checklist
Authors
Abstract
Journal Name
Year
Title
5/5
Creates 1,000,000 NFT tokens for this article
Token Features:
  • ERC-1155 Standard NFT
  • 1 Million Supply per Article
  • Transferable via MetaMask
  • Permanent Blockchain Record
Blockchain QR Code
Scan with Saymatik Web3.0 Wallet
Gas fees required in SCI Coins
Buy SCI

Saymatik Web3.0 Wallet

Google Play
App Store