Visible-Light-Induced Oxidation/[3 + 2] Cycloaddition/Oxidative Aromatization to Construct Benzo[]carbazoles from 1,2,3,4-Tetrahydronaphthalene and Arylhydrazine Hydrochlorides.

Visible-Light-Induced Oxidation/[3 + 2] Cycloaddition/Oxidative Aromatization to Construct Benzo[]carbazoles from 1,2,3,4-Tetrahydronaphthalene and Arylhydrazine Hydrochlorides.

Shen, Jiaxuan;Li, Nannan;Yu, Yanjiang;Ma, Chunhua;
Organic letters 2019
198
shen2019visiblelightinducedorganic

Abstract

An efficient synthesis of benzo[]carbazoles via visible-light-induced tandem oxidation/[3 + 2] cycloaddition/oxidative aromatization reactions was reported. The benzylic C(sp)-H of tetrahydronaphthalene was activated through visible-light photoredox catalyst with oxygen as the clean oxidant under mild reaction conditions. This protocol proceeds efficiently with broad substrate scope, and the mechanism study was performed.

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ID: 26442
Ref Key: shen2019visiblelightinducedorganic
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Article ID:
26442
Unique Identifier:
10.1021/acs.orglett.9b02939
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