Capture and characterization of a reactive haem–carbenoid complex in an artificial metalloenzyme
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Capture and characterization of a reactive haem–carbenoid complex in an artificial metalloenzyme

Takahiro Hayashi;Matthias Tinzl;Takahiro Mori;Ute Krengel;Jonny Proppe;Janne Soetbeer;Daniel Klose;Gunnar Jeschke;Markus Reiher;Donald Hilvert;Takahiro Hayashi;Matthias Tinzl;Takahiro Mori;Ute Krengel;Jonny Proppe;Janne Soetbeer;Daniel Klose;Gunnar Jeschke;Markus Reiher;Donald Hilvert;
nature catalysis 2018 Vol. 1 pp. 578-584
241
hayashi2018naturecapture

Abstract

A haem–carbenoid has been proposed to be involved in abiological enzymatic reactions. Now, Hilvert and co-workers provide crystallographic evidence for a haem–carbenoid intermediate as the reactive species in an olefin cyclopropanation reaction catalysed by an artificial metalloenzyme.

Keywords

Biocatalysis X-ray crystallography enzymes iron enzyme mechanisms

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DOI:
doi:10.1038/s41929-018-0105-6
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https://dx.doi.org/10.1038/s41929-018-0105-6

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