design of spin-frustrated monomer-type c60•− mott insulator
;Akihiro Otsuka;Dmitri V. Konarev;Rimma N. Lyubovskaya;Salavat S. Khasanov;Mitsuhiko Maesato;Yukihiro Yoshida;Gunzi Saito
turk kardiyoloji dernegi arsivi2018Vol. 8pp. 115-
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otsuka2018crystalsdesign
Abstract
Spin-frustrated monomer-type Mott insulator C60•− solids are discussed in this review article. For the C60•− solids, the interfullerene center-to-center distance (r) is the key parameter that controls the competition between covalent bond-formation, itinerancy, and spin frustration. Eight C60•− salts with various compositions and dimensionalities are reviewed. In all of these C60•− salts except one, neither bond-formation nor long-range magnetic ordering was observed down to low temperatures. A plot of Weiss temperature (|ΘCW|) against r shows that |ΘCW| grows rapidly below r = 10.0 Å.