redetermination of catena-poly[[chloridolead(ii)]-μ2-chlorido-di-μ2-thiourea-κ4s:s] at 100 k

redetermination of catena-poly[[chloridolead(ii)]-μ2-chlorido-di-μ2-thiourea-κ4s:s] at 100 k

;Hafid Zouihri;Khalid Yamni;Youssef Messouss;Najib Tijani;Lahcen Messaoudi
lecture notes in civil engineering 2016 Vol. 1 pp. x161745-
167
zouihri2016iucrdataredetermination

Abstract

Although the structure rerefinement (CCD data at 100 K) of the polymeric lead(II) thiourea complex, [PbCl2·2tu]n where (tu = SCN2H4), basically confirmed the previous study based on integrated Weissenberg data recorded at room temperature [Nardelli & Fava (1959). Acta Cryst. 12, 727–732]; all atomic positions could be determined with significantly higher precision and accuracy. In addition, all H atoms could be located from difference maps, revealing details of the hydrogen-bonding scheme.

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