Direct synthesis of ESBO derivatives-¹⁸O labelled with dioxirane.
La Tegola, Stefano;Annese, Cosimo;Suman, Michele;Tommasi, Immacolata;Fusco, Caterina;D'Accolti, Lucia;
TheScientificWorldJournal2013Vol. 2013pp. 212156
196
la-tegola2013directthescientificworldjournal
Abstract
This work addresses a new approach developed in our laboratory, consisting in the application of isolated dimethyldioxirane (DDO, 1a) labelled with ¹⁸O for synthesis of epoxidized glyceryl linoleate (Gly-LLL, 2). We expect that this work could contribute in improving analytical methods for the determination of epoxidized soybean oil (ESBO) in complex food matrices by adopting an ¹⁸O-labelled-epoxidized triacylglycerol as an internal standard.