pd(ii)/hpmov-catalyzed direct oxidative coupling reaction of benzenes with olefins

pd(ii)/hpmov-catalyzed direct oxidative coupling reaction of benzenes with olefins

;Yasutaka Ishii;Yasushi Obora
Journal of ethnopharmacology 2010 Vol. 15 pp. 1487-1500
147
ishii2010moleculespd(ii)/hpmov-catalyzed

Abstract

The direct aerobic coupling reaction of arenes with olefins was successfully achieved by the use of Pd(OAc)2/molybdovanadophosphoric acid (HPMoV) as a key catalyst under 1 atm of dioxygen. This catalytic system could be extended to the coupling reaction of various substituted benzenes with olefins such as acrylates, aclrolein, and ethylene through the direct aromatic C-H bond activation.

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10.3390/molecules15031487
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