pd(ii)/hpmov-catalyzed direct oxidative coupling reaction of benzenes with olefins
;Yasutaka Ishii;Yasushi Obora
Journal of ethnopharmacology2010Vol. 15pp. 1487-1500
147
ishii2010moleculespd(ii)/hpmov-catalyzed
Abstract
The direct aerobic coupling reaction of arenes with olefins was successfully achieved by the use of Pd(OAc)2/molybdovanadophosphoric acid (HPMoV) as a key catalyst under 1 atm of dioxygen. This catalytic system could be extended to the coupling reaction of various substituted benzenes with olefins such as acrylates, aclrolein, and ethylene through the direct aromatic C-H bond activation.