The Special "Morse Code" between Solvent Polarity and Morphology Flexibility in in POSS-dendrimer supramolecular system.

The Special "Morse Code" between Solvent Polarity and Morphology Flexibility in in POSS-dendrimer supramolecular system.

Shan, Tianyu;Gao, Liang;Tong, Xiaoqian;Du, Qinqing;An, Zhihang;He, Huiwen;Lin, Jiaping;Chen, Si;Wang, Xu;
Chemistry (Weinheim an der Bergstrasse, Germany) 2019
217
shan2019thechemistry

Abstract

An amazing phenomenon of the relative magnitude of modulus of two liquid crystal (LC) gels is found inverted under/above their phase transition temperature TLC-iso, which is further proved to be caused by their diverse morphology flexibility. By testing the polarity of two LCs, we discovered that gelator POSS-G1-Boc self-assemble into more flexible structures in a relative low polar LC, while more rigid ones are formed in higher polar LC. Hence we established a fitting function to connect morphology flexibility with solvent polarity, which can even be generalized to a number of common solvents. Experimental observations and coarse-grained molecular dynamics simulations revealed that solvent polarity is just like the special "morse code", and each "morse code" corresponding to a specific morpholsogy flexibility.

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10.1002/chem.201901422
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