reaction of propargyltrimethylsilane magnesium bromide with aldimines: synthesis of 1-(alkylamino)-2-(trimethylsilyl)but-3-yne
Abstract
The reaction of propargylsilane magnesium bromide with aldimines provides in some cases, an isomeric mixture of three acetylenic amines 1, 2, 3 (1 and 2, as major products). The reaction has great potential and has been exploited for an efficient synthesis of the pure amine 2.
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225351
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