interactions between (me[sub]4[/sub]n)[sub]2[/sub](c[sub]2[/sub]o[sub]4[/sub])[sub]2[/sub]snph2•h[sub]2[/sub]o and snc[sub]l2[/sub]•2h[sub]2[/sub]o: (me[sub]4[/sub]n)[sub]2[/sub](c[sub]2[/sub]o[sub]4[/sub])[sub]2[/sub]snph[sub]2[/sub]•2sncl[sub]4[/sub] or (me[sub]4[/sub]n)[sub]2[/sub](c[sub]2[/sub]o[sub]4[/sub])[sub]2[/sub]sncl[sub]2[/sub]•2snphcl[sub]3[/sub] ? the mÖssbauer effect solution
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interactions between (me[sub]4[/sub]n)[sub]2[/sub](c[sub]2[/sub]o[sub]4[/sub])[sub]2[/sub]snph2•h[sub]2[/sub]o and snc[sub]l2[/sub]•2h[sub]2[/sub]o: (me[sub]4[/sub]n)[sub]2[/sub](c[sub]2[/sub]o[sub]4[/sub])[sub]2[/sub]snph[sub]2[/sub]•2sncl[sub]4[/sub] or (me[sub]4[/sub]n)[sub]2[/sub](c[sub]2[/sub]o[sub]4[/sub])[sub]2[/sub]sncl[sub]2[/sub]•2snphcl[sub]3[/sub] ? the mÖssbauer effect solution

;Libasse Diop;Hayat Qamar Kane
Mineralogical Magazine 2010 Vol. 11 pp. 389-392
137
diop2010scientificinteractions

Abstract

The study of the interactions between (Me[sub]4[/sub]N)[sub]2[/sub](C[sub]2[/sub]O[sub]4[/sub])SnPh[sub]2[/sub]•H[sub]2[/sub]O and SnCl[sub]2[/sub]•2H[sub]2[/sub]O in EtOH has yielded a trinuclear adduct which Mössbauer study has allowed to choose (Me[sub]4[/sub]N)[sub]2[/sub](C[sub]2[/sub]O[sub]4[/sub])[sub]2[/sub]SnCl[sub]2[/sub]•2SnPhCl[sub]3[/sub] rather than (Me[sub]4[/sub]N)[sub]2[/sub](C[sub]2[/sub]O[sub]4[/sub])[sub]2[/sub]SnPh[sub]2[/sub]•2SnCl[sub]4[/sub] for formula, the oxalate anion behaving as a bichelating ligand, the environment around the tin (IV) centre being octahedral.

Keywords

appearance of snphcl3 in situchemical technology

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