[(1,2,5,6-η)-cycloocta-1,5-diene](1-ethyl-3-isopropyl-1,3-imidazol-2-ylidene-κc2)(triphenylphosphane-κp)iridium(i) tetrafluoridoborate

[(1,2,5,6-η)-cycloocta-1,5-diene](1-ethyl-3-isopropyl-1,3-imidazol-2-ylidene-κc2)(triphenylphosphane-κp)iridium(i) tetrafluoridoborate

;Karam B. Idrees;William J. Rutledge;Sue A. Roberts;Edward Rajaseelan
lecture notes in civil engineering 2017 Vol. 2 pp. x171411-
190
idrees2017iucrdata[(1,2,5,6-)-cycloocta-1,5-diene](1-ethyl-3-isopropyl-1,3-imidazol-2-ylidene-c2)(triphenylphosphane-p)iridium(i)

Abstract

In the title compound, [Ir(C8H12)(C8H14N2)(C18H15P)]BF4, the cationic complex has the anticipated square-planar geometry. The asymmetric unit comprises the iridium complex and one tetrafluoridoborate anion. The space group is non-centrosymmetric, with the Flack parameter of 0.007 (3) well determined, and confirms the hand for the complex cation. This compound shows promising catalytic activity in transfer hydrogenation reactions.

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ID: 215461
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