This paper investigates the multiuser transmission network with an energy harvesting (EH) cooperative relay, where a source transmits independent information to multiple destinations with the help of an energy constrained relay. The relay can harvest energy from the radio frequency (RF) signals transmitted from the source, and it helps the multiuser transmission only by consuming the harvested energy. By adopting the time switching and the power splitting relay receiver architectures, we firstly propose two protocols, the time switching cooperative multiuser transmission (TSCMT) protocol and the power splitting cooperative multiuser transmission (PSCMT) protocol, to enable the simultaneous information processing and EH at the relay for the system. To evaluate the system performance, we theoretically analyze the system outage probability for the two proposed protocols and then derive explicit expressions for each of them, respectively. Numerical results are provided to demonstrate the accuracy of our analytical results and reveal that compared with traditional noncooperative scheme our proposed protocols are green solutions to offer reliable communication and lower system outage probability without consuming additional energy. In particular, for the same transmit power at the source, the PSCMT protocol is superior to the TSCMT protocol to obtain lower system outage probability.