kinetics and thermodynamics of the dissolution of steel in 1 mol l−1 hydrochloric acid solution in the presence of silene marmarica as environmentally friendly corrosion inhibitor

kinetics and thermodynamics of the dissolution of steel in 1 mol l−1 hydrochloric acid solution in the presence of silene marmarica as environmentally friendly corrosion inhibitor

;O.A. Abdullatef
9th international conference on intelligent systems 2018: theory, research and innovation in applications, is 2018 - proceedings 2015 Vol. 24 pp. 505-511
213
abdullatef2015egyptiankinetics

Abstract

The dissolution of steel in 1 mol L−1 hydrochloric acid solution containing different concentrations of Silene Marmarica was studied at different temperatures 30, 35, 40 and 45 °C using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques. The results showed that the presence of Silene Marmarica inhibits the corrosion of steel in 1 mol L−1 hydrochloric acid solution and the inhibition efficiency increased with the increasing concentration of Silene Marmarica. The Langmuir adsorption isotherm was used to calculate the thermodynamic parameter ΔGads° from experimental data obtained during the course of this research. The activation parameters Ea, ΔH∗ and ΔS∗ were calculated using the Arrhenius equation in conjunction with experimental data also acquired during the course of our studies.

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0x95644003c57E6F55A65596E3D9Eac6813e3566dA
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213430
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10.1016/j.ejpe.2015.03.003
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