kinetics and thermodynamics of the dissolution of steel in 1 mol l−1 hydrochloric acid solution in the presence of silene marmarica as environmentally friendly corrosion inhibitor
;O.A. Abdullatef
9th international conference on intelligent systems 2018: theory, research and innovation in applications, is 2018 - proceedings2015Vol. 24pp. 505-511
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abdullatef2015egyptiankinetics
Abstract
The dissolution of steel in 1 mol L−1 hydrochloric acid solution containing different concentrations of Silene Marmarica was studied at different temperatures 30, 35, 40 and 45 °C using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques. The results showed that the presence of Silene Marmarica inhibits the corrosion of steel in 1 mol L−1 hydrochloric acid solution and the inhibition efficiency increased with the increasing concentration of Silene Marmarica. The Langmuir adsorption isotherm was used to calculate the thermodynamic parameter ΔGads° from experimental data obtained during the course of this research. The activation parameters Ea, ΔH∗ and ΔS∗ were calculated using the Arrhenius equation in conjunction with experimental data also acquired during the course of our studies.