synthesis of (2r,5r)-2-amino-5-hydroxyhexanoic acid by intramolecular cycloaddition
Abstract
The title compound was synthesized from sorbic acid by an eight step sequence. The key step was the stereospecific intramolecular Diels-Alder reaction of the acylnitroso derivative of N-sorbyl-L-proline (5). L-Proline served as a temporary tether which directed both the stereochemistry and the regiochemistry of the cycloaddition.
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211168
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211168
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10.3390/30300080
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Scimatic Chain (ID: 481)
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