refractory black carbon mass concentrations in snow and ice: method evaluation and inter-comparison with elemental carbon measurement

refractory black carbon mass concentrations in snow and ice: method evaluation and inter-comparison with elemental carbon measurement

;S. Lim;X. Faïn;M. Zanatta;J. Cozic;J.-L. Jaffrezo;P. Ginot;P. Laj
bioorganic & medicinal chemistry 2014 Vol. 7 pp. 3307-3324
138
lim2014atmosphericrefractory

Abstract

Accurate measurement of black carbon (BC) mass concentrations in snow and ice is crucial for the assessment of climatic impacts. However, it is difficult to compare methods used to assess BC levels in the literature as they are not the same. The single particle soot photometer (SP2) method appears to be one of the most suitable to measure low concentrations of BC in snow and ice. In this paper, we evaluated a method for the quantification of refractory BC (rBC) in snow and ice samples coupling the SP2 with the APEX-Q nebulizer. The paper reviews all the steps of rBC determination, including SP2 calibration, correction for rBC particle aerosolization efficiency (75 ± 7% using the APEX-Q nebulizer), and treatment of the samples. In addition, we compare the SP2 method and the thermal–optical method – Sunset organic carbon (OC) / elemental carbon (EC) aerosol analyzer with EUSAAR2 protocol – using snow and firn samples with different characteristics from the Greenland Summit, the French Alps, the Caucasus, and the Himalayas. Careful investigation was undertaken of analytical artifacts that potentially affect both methods. The SP2-based rBC quantification may be underestimated when the SP2 detection range does not cover correctly the existing size distribution of the sample. Thermal–optical EC measurements can be underestimated by low filtration efficiency of quartz fiber filter before analysis or dust properties (concentration and type), and overestimated by pyrolyzed OC artifacts during EC analysis. These results underline the need for careful assessment of the analytical technique and procedure for correct data interpretation.

Citation

ID: 210068
Ref Key: lim2014atmosphericrefractory
Use this key to autocite in SciMatic or Thesis Manager

References

Blockchain Verification

Account:
NFT Contract Address:
0x95644003c57E6F55A65596E3D9Eac6813e3566dA
Article ID:
210068
Unique Identifier:
10.5194/amt-7-3307-2014
Network:
Scimatic Chain (ID: 481)
Loading...
Blockchain Readiness Checklist
Authors
Abstract
Journal Name
Year
Title
5/5
Creates 1,000,000 NFT tokens for this article
Token Features:
  • ERC-1155 Standard NFT
  • 1 Million Supply per Article
  • Transferable via MetaMask
  • Permanent Blockchain Record
Blockchain QR Code
Scan with Saymatik Web3.0 Wallet

Saymatik Web3.0 Wallet