Results are presented on the effect of firing rate on pressure pulse in charge camera and fracture stress during spalling. Results are presented of comparative calculations using the equations of autocatalytic reactions of firing rates and escape of reaction products for the system of sodium chlorate - polythene (propylene) in pipe shape. Dependences are obtained of firing rate on concentration of gas generating mixture, its density, components size distribution and cartridge case size. Experimental and computational data were used to consider the conditions of firing turning into explosion for compositions based on sodium chlorate and hydrocarbons in layered and powdered systems. The relation is retrieved between the technological parameters of mining activities (blast hole to blast hole distance, blast hole diameter, depth of cartridge placement) and specific cartridge consumption along the spalling line with gas generators going off.