Oscillatory structural forces between charged interfaces in solutions of oppositely charged polyelectrolytes.

Oscillatory structural forces between charged interfaces in solutions of oppositely charged polyelectrolytes.

Kubiak, Katarzyna;Maroni, Plinio;Trefalt, Gregor;Borkovec, Michal;
Soft matter 2020
187
kubiak2020oscillatorysoft

Abstract

Forces between negatively charged micron-sized silica particles were measured in aqueous solutions of cationic polyelectrolytes with an atomic force microscope (AFM). In these oppositely charged systems, damped oscillatory force profiles were systematically observed in systems at higher polyelectrolyte concentrations, typically around few g L-1. The wavelength of these oscillations is decreasing with increasing concentration. When the wavelength and concentration are normalized with the cross-over concentration, universal power-law dependence is found. Thereby, the corresponding scaling exponent changes from 1/3 in the dilute regime to 1/2 in the semi-dilute regime. This dependence is the same as in the like-charged systems, which were described in the literature earlier. This common behavior suggests that these oscillatory forces are related to the structuring of the polyelectrolyte solutions. The reason that the oppositely charged systems behave similarly to like-charged ones is that the former systems undergo a charge reversal due to the adsorption of the polyelectrolytes to the oppositely charged surface, whereby sufficiently homogeneous adsorbed layers are being formed. The main finding of the present study is that at higher polyelectrolyte concentrations such oscillatory forces are the rule, including the oppositely charged ones.

Citation

ID: 188247
Ref Key: kubiak2020oscillatorysoft
Use this key to autocite in SciMatic or Thesis Manager

References

Blockchain Verification

Account:
NFT Contract Address:
0x95644003c57E6F55A65596E3D9Eac6813e3566dA
Article ID:
188247
Unique Identifier:
10.1039/d0sm01257b
Network:
Scimatic Chain (ID: 481)
Loading...
Blockchain Readiness Checklist
Authors
Abstract
Journal Name
Year
Title
5/5
Creates 1,000,000 NFT tokens for this article
Token Features:
  • ERC-1155 Standard NFT
  • 1 Million Supply per Article
  • Transferable via MetaMask
  • Permanent Blockchain Record
Blockchain QR Code
Scan with Saymatik Web3.0 Wallet

Saymatik Web3.0 Wallet