Downsizing of robust Fe-triazole@SiO spin-crossover nanoparticles with ultrathin shells.
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Downsizing of robust Fe-triazole@SiO spin-crossover nanoparticles with ultrathin shells.

Torres-Cavanillas, R;Lima-Moya, L;Tichelaar, F D;Zandbergen, H W;Giménez-Marqués, M;Coronado, E;
Dalton transactions (Cambridge, England : 2003) 2019
252
torrescavanillas2019downsizingdalton

Abstract

A chemical protocol to design robust hybrid [Fe(Htrz)2(trz)](BF4)@SiO2 nanoparticles (NPs) with sizes as small as 28 nm and ultrathin silica shells below 3 nm has been developed. These NPs present a characteristic abrupt spin transition with a subsequent decrease in the width of the thermal hysteresis upon reducing the NP size.

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DOI:
10.1039/c9dt02086a

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ID: 1881
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