This paper applies Life Cycle Assessment methodology to aid in the decision making to select the preventive measure against chloride corrosion in concrete structures that works best for the socio-economic context of the structure. The assumed model combines the concepts of Life Cycle Cost Analysis and Social Life Cycle Analysis to assess the impacts on users derived from the maintenance activities associated with each alternative analyzed in terms of economic costs. The model has been applied to a prestressed concrete bridge to obtain a preventive measure that can reduce the total costs incurred over the period of analysis by up to 58.5% compared to the cost of the current solution.