Force-driven reversible liquid-gas phase transition mediated by elastic nanosponges.

Force-driven reversible liquid-gas phase transition mediated by elastic nanosponges.

Nomura, Keita;Nishihara, Hirotomo;Yamamoto, Masanori;Gabe, Atsushi;Ito, Masashi;Uchimura, Masanobu;Nishina, Yuta;Tanaka, Hideki;Miyahara, Minoru T;Kyotani, Takashi;
Nature communications 2019 Vol. 10 pp. 2559
347
nomura2019force-driven

Abstract

Nano-confined spaces in nanoporous materials enable anomalous physicochemical phenomena. While most nanoporous materials including metal-organic frameworks are mechanically hard, graphene-based nanoporous materials possess significant elasticity and behave as nanosponges that enable the force-driven liquid-gas phase transition of guest molecules. In this work, we demonstrate force-driven liquid-gas phase transition mediated by nanosponges, which may be suitable in high-efficiency heat management. Compression and free-expansion of the nanosponge afford cooling upon evaporation and heating upon condensation, respectively, which are opposite to the force-driven solid-solid phase transition in shape-memory metals. The present mechanism can be applied to green refrigerants such as HO and alcohols, and the available latent heat is at least as high as 192 kJ kg. Cooling systems using such nanosponges can potentially achieve high coefficients of performance by decreasing the Young's modulus of the nanosponge.

Citation

ID: 1583
Ref Key: nomura2019force-driven
Use this key to autocite in SciMatic or Thesis Manager

References

Blockchain Verification

Account:
NFT Contract Address:
0x95644003c57E6F55A65596E3D9Eac6813e3566dA
Article ID:
1583
Unique Identifier:
10.1038/s41467-019-10511-7
Network:
Scimatic Chain (ID: 481)
Loading...
Blockchain Readiness Checklist
Authors
Abstract
Journal Name
Year
Title
5/5
Creates 1,000,000 NFT tokens for this article
Token Features:
  • ERC-1155 Standard NFT
  • 1 Million Supply per Article
  • Transferable via MetaMask
  • Permanent Blockchain Record
Blockchain QR Code
Scan with Saymatik Web3.0 Wallet

Saymatik Web3.0 Wallet