chlorido(1-cyclopentylidene-4-ethylthiosemicarbazidato-κ2n1,s)diphenyltin(iv)

chlorido(1-cyclopentylidene-4-ethylthiosemicarbazidato-κ2n1,s)diphenyltin(iv)

;Frank R. Fronczek;Lungile Sitole;Ramaiyer Venkatraman
acta structilia 2009 Vol. 65 pp. m1653-m1654
1
fronczek2009actachlorido(1-cyclopentylidene-4-ethylthiosemicarbazidato-κ2n1,s)diphenyltin(iv)

Abstract

The Sn atom in the title compound, [Sn(C6H5)2(C8H14N3S)Cl], is pentacoordinated with a trigonal-bipyramidal coordination geometry. The 1-cyclopentylidene-4-ethylthiosemicarbazidate (cpetsc) ligand coordinates through the S atom and the N atom bonds to the cyclopentyl group, forming a five-membered ring with the Sn center. The chloride ligand and the coordinated N atom are in axial positions. In the crystal structure, intermolecular N—H...Cl hydrogen bonds form chains along [101].

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