degradação do pesticida padron® por processos fotoquímicos utilizando luz artificial e solar degradation of padron® by photochemical processes using artificial and sunlight radiation

degradação do pesticida padron® por processos fotoquímicos utilizando luz artificial e solar degradation of padron® by photochemical processes using artificial and sunlight radiation

;Silvio César Godinho Teixeira;Maria Cristina Canela
greece and rome 2007 Vol. 30 pp. 1830-1834
190
teixeira2007qumicadegradao

Abstract

Destruction of Padron® (dye and picloram) was evaluated using a photoreactor and a solar reactor. Photolysis was observed using only a germicide lamp (GL). Black light (BL) and H2O2 (172 mmol L-1) promoted a conversion of 49% and 6% of dye and picloram, respectively. Photocatalytic processes were more efficient using TiO2/GL (96%-dye; 60%-picloram) than TiO2/BL (44%-dye; 40%-picloram). Photolysis using sunlight was not observed during PadronÒ recirculation in the reactor constructed with four borosilicate tubes. Meanwhile, adding H2O2 resulted in 12% conversion of dissolved organic compounds. Finally, the most efficient mineralization (60%) was obtained using the Fenton reaction ( H2O2-176 mmol L-1; FeSO4x6H2O-90 mmol L-1) and sunlight.

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