on atom–atom `short contact' bonding interactions in crystals
;Claude Lecomte;Enrique Espinosa;Cherif F. Matta
european journal of orthopaedic surgery & traumatology : orthopedie traumatologie2015Vol. 2pp. 161-163
113
lecomte2015iucrjon
Abstract
Professor Dunitz questions the usefulness of ascribing crystalline structural stability to individual atom–atom intermolecular interactions viewed as bonding (hence stabilizing) whenever linked by a bond path. An alternative view is expressed in the present essay that articulates the validity and usefulness of the bond path concept in a crystallographic and crystal engineering context.